In brief

The crystal structure of sodium molybdate, a compound which can be used to grow large monolayer crystals with useful conducting properties.

© 2019 A*STAR Institute of Materials Research and Engineering

Bigger, better conductive crystals a boon for electronics

23 Sep 2019

A*STAR researchers have developed a method to generate large monolayer crystals of molybdenum disulfide for use in scaled-down and flexible electronics.

Electronic devices are becoming smaller in size, yet the number of functions each gadget can perform is constantly increasing. Driving these improvements is an essential component known as field-effect transistor (FET). The most common FET in modern times—called MOSFET, short for metal–oxide–semiconductor field-effect transistor—was built using silicon around the end of the 1950s.

However, silicon-based FETs that are miniaturized below a certain size face issues arising from the short channel effect, which negatively impacts the flow and control of electric current. Scientists led by Dongzhi Chi at the Institute of Materials Research and Engineering (IMRE), in collaboration with colleagues at the National University of Singapore and Shenzhen University, China, are now seeking to circumvent this limitation with an alternative material: molybdenum disulfide.

Known to possess high electron mobility and immunity to the short channel effect, molybdenum disulfide is superior to silicon in downscaled digital electronic devices. Yet, growing molybdenum disulfide crystals at scale remains difficult.

“The reported grain size of single-crystal, sulfurization-grown molybdenum disulfide was typically limited to several tens of micrometers or less with conventional molybdenum precursors such as molybdenum metal and molybdenum oxides,” explained IMRE’s Shi Wun Tong, the lead author on the study. “This limited the fabrication and demonstration of high-performance devices on large-area and grain boundary-free molybdenum disulfide single crystals.”

The group therefore explored the use of an alternative crystal precursor, sodium molybdate dihydrate, which not only provides the initial molybdenum for crystal formation, but also enhances the nucleation and lateral growth of the crystal, enabling much larger crystals to be produced. Using this method, the team managed to grow monolayer molybdenum disulfide crystals larger than 300 micrometers.

Remarkably, FETs containing these large monolayer crystals exhibited electron mobility approaching 90 cm2 V-1 s-1, outstripping that of crystals generated through existing methods, which typically display electron mobility ranging between 8–63 cm2 V-1 s-1.

Now, the researchers are looking to incorporate these crystals with various self-powered, ultrathin and flexible electronics. Tong also noted that the ability to synthesize large-sized monolayer crystals paves the way for other applications. “Our approach and findings should enable researchers to design or conduct high-throughput experiments where strictly monolayer and grain boundary-free single crystals are required, such as for quantum optics, valleytronics and piezoelectric applications,” said Tong.

The A*STAR-affiliated researchers contributing to this research are from the Institute of Materials Research and Engineering (IMRE).

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Tong, S.W., Medina, H., Liao, W., Wu, J., Wu, W., et al. Employing a Bifunctional Molybdate Precursor To Grow the Highly Crystalline MoS2 for High-Performance Field-Effect Transistors. ACS Applied Materials and Interfaces 11, 14239-14248 (2019) | article

About the Researcher

Shi Wun Tong obtained her PhD degree from the City University of Hong Kong in 2005. She is currently a Research Scientist in the Department of Electronic Materials at A*STAR’s Institute of Materials Research and Engineering (IMRE). Her research revolves around the growth and characterization of two-dimensional transition metal dichalcogenide materials and graphene, as well as the exploration of their optoelectronic properties.

This article was made for A*STAR Research by Wildtype Media Group